Beilstein J. Nanotechnol.2011,2, 720–726, doi:10.3762/bjnano.2.78
based on a Frenkel exciton Hamiltonian. Furthermore, intriguing new bands in the absorption and fluorescence spectra of the smaller macrocycles disclose the dominance of their ring strain.
Keywords: conjugatedmacrocycles; Frenkel exciton model; oligothiophene; photophysical properties; Introduction
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Scheme 1:
Chemical structure of the oligothiophene macrocycles (series I and II). The coordinate system used ...